典型地区农用地污染调查及风险管控标准探讨

针对《土壤污染风险管控标准——农用地土壤污染风险管控标准》(GB 15618—2018),提出以土壤中全量浓度筛选值和管控值作为衡量农用地土壤污染风险管控的标准,对湖南省部分稻田农用地土壤及点对点稻米样品中镉、铅、砷、汞的总量和有效态浓度及稻米中含量进行监测,根据重金属总量浓度分为低风险、中风险、高风险3组。结果显示:(1)土壤及稻米中镉含量基本为随着风险级别的升高而增加,铅、砷在土壤和稻米中含量无规律性结果,汞监测结果均为未检出。(2)低风险组稻米镉超标率为12. 0%,高风险组稻米镉达标率为33. 3%,表明利用总量浓度对农用地土壤潜在风险进行分组存在一定的局限性。(3)依据4种重金属在土壤中总量及稻米(早稻)中含量情况,对风险级别进行调整并综合判断:有58个样品为低风险组,占样品总数的68. 2%,超标率为零;有15个样品为中风险组,占样品总数的17. 7%,超标率为80. 0%;有12个样品为高风险组,占样品总数的14. 1%,超标率为100. 0%。调整后评价结果与上述标准的划分目标更接近,能够提高上述标准的准确性和实用性。     

Effects of T-2 toxin on histopathology,fatty acid and water distribution of shrimp (Litopenaeus vannamei) muscle

T-2 toxin (T-2), one of the naturally occurring mycotoxins, often accumulates in aquatic animals from contaminated feed. Shrimp (n?=?30 per group) were fed with different concentrations (0, 0.5, 1.5, 4.5 and 13.5?mg kg^?1) of T-2 for 20?days. Changes in histopathology, fatty acid and water distribution of shrimp muscle were analyzed. Histopathology of shrimp muscle showed dose-dependent marked degenerative and necrotic changes on exposure to dietary T-2. The T-2 significantly (P?<?0.05) affected the muscle fatty acid composition. ∑SFA, ∑MUFA and ∑PUFA initially decreased and then increased slowly in the high-dosed groups. C16:0, C18:1n-9 and C18:2n-6 were the main saturated fatty acid (SFA), monounsaturated fatty acid (MUFA) and polyunsaturated fatty acid (PUFA), respectively. Also, T-2 significantly affected water distribution in shrimp muscle. High doses of T-2 reduced free water content, resulting in a reduction in the water holding capacity and hence changes to the shrimp muscle quality. Collectively, these results illustrated that T-2 significantly affects the fatty acid and water distribution, and also muscle histopathology, all of which would result in a reduction in the quality and nutritional value of shrimp.     

长江三角洲地区机场体系基础设施效率的时空演化

机场效率评价与分析是相关学者关注的热点。采用DEA方法，以长江三角洲地区机场体系为实证，以基础设施的投入与产出为关注点，探讨2000~2014年间机场效率的时空演化及其影响因素。结果表明：研究期间长三角地区机场体系基础设施效率总体较低，空间上呈南高北低，东高西低特征；在时空演化上，基础设施效率呈提升态势，机场间的差异性呈降低趋势，各机场演化过程具有明显差别，但总体上效率高的机场，其演化过程中变异系数较低，反之亦然；近15a来机场基础设施效率的差异性演化并未引起区域空间格局大的变动，但江苏沿海地区的机场效率优势正在逐步形成。通过效率分解，发现规模效率是影响长三角地区机场体系综合技术效率的主要原因，正是规模效率的低下引致了综合技术效率低下。机场基础设施效率及其演化是机场自身发展状况（内在因素）的综合反映，同时深受区域发展水平、机场竞争态势以及机场交通区位等诸多外部因素影响。最后，讨论了提升长三角地区机场体系基础设施效率的可能路径。     

A comparative study of vocational education and occupational safety and health training in China and the UK

In order to enhance Chinese workers’ occupational safety awareness, it is essential to learn from developed countries’ experiences. This article investigates thoroughly occupational safety and health (OSH) in China and the UK; moreover, the article performs a comparison of Chinese and British OSH training-related laws, regulations and education system. The following conclusions are drawn: China’s work safety continues to improve, but there is still a large gap compared with the UK. In China a relatively complete vocational education and training (VET) system has been established. However, there exist some defects in OSH. In the UK, the employer will not only pay attention to employees’ physiological health, but also to their mental health. The UK’s VET is characterized by classification and grading management, which helps integrate OSH into the whole education system. China can learn from the UK in the development of policies, VET and OSH training.     

Adsorption of Ammonium by Graphene Oxide-Based Composites Prepared by UV Irradiation and Using as Slow-Release Fertilizer

A novel sodium alginate-grafted poly(acrylic acid)/graphene oxide (NaAlg-g-PAA/GO) composite hydrogel was prepared via ultraviolet irradiation, and characterized by infrared spectroscopy spectrometer. X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy. It was employed to adsorb NH₄⁺ from aqueous solution and used as slow-release nitrogen fertilizers (SNFs). Result indicated that the adsorption process for NH₄⁺ reached equilibrium within 50 min, with the adsorption capacity of 6.6 mmol g^?1 even if 30 wt% GO was incorporated. The results of adsorption kinetic and isotherm were well described by the pseudo-second-order and Freundlich model. The thermodynamics analysis showed the adsorption process was spontaneous. The study indicated excellent water-holding ratio of soil with 2 wt% SNFs was 81.2%, and nitrogen release was up to 55.1% within 40 days in soil. Overall, NaAlg-g-PAA/GO could be considered as an efficient adsorbent for the recovery of nitrogen with the agronomic reuse as a fertilizer.     

g-C_3N_4/C@Bi_2MoO_6复合光催化剂的制备及其光催化活性

通过水热合成法和液相沉积法制备g-C_3N_4/C@Bi_2MoO_6复合光催化剂,并采用X射线衍射、扫描电子显微镜、氮气吸脱附、紫外-可见漫反射等技术对其进行表征。研究了可见光下g-C_3N_4/C@Bi_2MoO_6催化降解罗丹明B(Rh B)的影响因素,并对其光催化反应机理进行初步探讨。实验结果表明:g-C_3N_4掺杂量为60%(w)时g-C_3N_4/C@Bi_2MoO_6的光催化活性最高;在60%g-C_3N_4/C@Bi_2MoO_6的投加量为1.00 g/L、初始Rh B质量浓度为2.50 mg/L、可见光照射150 min的条件下,Rh B的降解率达到97.90%;在g-C_3N_4/C@Bi_2MoO_6光催化降解体系中,h~+和·O_2~-是主要活性物种。     

三维电极电Fenton氧化法处理染料废水

采用三维电极电Fenton氧化法处理实际染料废水,探究了染料废水处理效果的影响因素。实验结果表明：以钌铱镀层钛电极为阳极、不锈钢板为阴极、粉末活性炭为颗粒电极,在粉末活性炭投加量为2.0 g/L、电流密度为0.5 mA/mm²、极板间距为3 cm、pH为2.0、硫酸亚铁投加量为0.50 g/L的最优工艺条件下,反应2 h后COD、TOC、氨氮、色度的去除率达到最大,分别为62.80%、41.15%、42.48%和95.00%;粉末活性炭作为颗粒电极可使染料废水COD去除率提高18个百分点;重复使用10次的处理效果与第2次基本持平。     

A fractal derivative model to quantify bed-load transport along a heterogeneous sand bed

Environmental Fluid Mechanics - Bed-load transport is a complex process exhibiting anomalous dynamics, which cannot be efficiently described using the traditional advection–diffusion...     

Understanding interactions between urban development policies and GHG emissions: A case study in Stockholm Region

Human-induced urban growth and sprawl have implications for greenhouse gas (GHG) emissions that may not be included in conventional GHG accounting methods. Improved understanding of this issue requires use of interactive, spatial-explicit social–ecological systems modeling. This paper develops a comprehensive approach to modeling GHG emissions from urban developments, considering Stockholm County, Sweden as a case study. GHG projections to 2040 with a social–ecological system model yield overall greater emissions than simple extrapolations in official climate action planning. The most pronounced difference in emissions (39% higher) from energy use single-residence buildings resulting from urban sprawl. And this difference is not accounted for in the simple extrapolations. Scenario results indicate that a zoning policy, restricting urban development in certain areas, can mitigate 72% of the total emission effects of the model-projected urban sprawl. The study outcomes include a decision support interface for communicating results and policy implications with policymakers.

     

国家重点生态功能区县域环境监测质量评价方法及应用示范

以国家重点生态功能区县域环境监测质量评价为目标,综合应用德尔菲法、层次分析法和模糊综合评价法,构建了国家重点生态功能区县域环境监测质量评价方法,并确定了评价因子、权重系数、计算方法。该方法评价指标共分为三层:第一层为目标层,即国家重点生态功能区县域环境监测质量;第二层为准则层,包括人员及资质、现场监测、实验室管理、报告编制及数据上报;第三层为方案层,包括人员操作、持证上岗、资质认定、人员培训、水质布点采样流转情况、空气自动站运维情况、现场质控实施情况、实验室环境条件、样品试剂的保存与管理、仪器检定与校准、实验室质量控制实施情况、数据填报软件运行情况、监测报告规范性等13个评价要素。经矩阵一致性检验确定了各评价要素的权重,将该权重与各要素得分运算后得到县域环境监测质量评价结果。在此基础上,选取广东、山西、陕西、四川和青海等5个省份的15个国家重点生态功能区县域作为典型区开展了实地调研,并应用评价体系对其进行了监测质量等级评价。结果表明,15个典型县域中,环境监测质量等级为优的县域占13.3%,一般、较差的县域分别占66.7%、20%。县域环境监测承担单位在资质、报告编制及数据上报方面表现较好,在现场监测、人员操作方面问题突出,在实验室管理方面有待提升。